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quantum phase transition : ウィキペディア英語版
quantum phase transition
In physics, a quantum phase transition (QPT) is a phase transition between different quantum phases (phases of matter at zero temperature). Contrary to classical phase transitions, quantum phase transitions can only be accessed by varying a physical parameter—such as magnetic field or pressure—at absolute zero temperature. The transition describes an abrupt change in the ground state of a many-body system due to its quantum fluctuations. Such a quantum phase transition can be a second-order phase transition.
==Classical description==

To understand quantum phase transitions, it is useful to contrast them to classical phase transitions (CPT) (also called thermal phase transitions). A CPT describes a cusp in the thermodynamic properties of a system. It signals a reorganization of the particles; A typical example is the freezing transition of water describing the transition between liquid and solid. The classical phase transitions are driven by a competition between the energy of a system and the entropy of its thermal fluctuations. A classical system does not have entropy at zero temperature and therefore no phase transition can occur. Their order is determined by the first discontinuous derivative of a thermodynamic potential.
A phase transition from water to ice, for example, involves latent heat (a discontinuity of the heat capacity C = \partial U/\partial T) and is of first order. A phase transition from a ferromagnet to a paramagnet is continuous and is of second order. (See phase transition for Ehrenfest's classification of phase transitions by the derivative of free energy which is discontinuous at the transition).
These continuous transitions from an ordered to a disordered phase are described by an order parameter, which is zero in the
disordered and non-zero in the ordered phase. For the aforementioned ferromagnetic transition, the order parameter would represent the total magnetization of the system.
Although the thermodynamic average of the order parameter is zero in the disordered state, its fluctuations can be non-zero and become
long-ranged in the vicinity of the critical point, where their typical length scale ''ξ'' (correlation length) and typical fluctuation decay time scale ''τc'' (correlation time) diverge:
: \xi \propto |\epsilon |^\,\,= \left (\frac\right )^
: \tau_c \propto \xi^ \propto |\epsilon |^,
where
:\epsilon = \frac
is defined as the relative deviation from the critical temperature ''Tc''. We call ''ν'' the (correlation length) ''critical exponent'' and ''z'' the ''dynamical critical exponent''. Critical behavior of finite temperature phase transitions is fully described by classical thermodynamics; quantum mechanics does not play any role even if the actual phases require a quantum mechanical description (e.g. superconductivity).

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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